Hi Flyingmark,
The Orientation app is included with the Leap Motion software installed with the drivers and service, etc, so it isn't in the Airspace store on its own.
The current API gives you the positions of the hand and the position of the tips of any fingers it detects. The Orientation app uses the same API available to external developers.
You can use a the data from the API to control a human-like hand model. It is challenging to make things move with a life-like appearance, though, given just the finger tips. (I think it can be done, but it isn't a matter of simply moving the model finger tips using the finger tip positions.)
Currently, only one Leap Motion device is supported per computer. Depending on what you are doing, you can use virtual machines (or even multiple physical computers) to get data from multiple devices. Interference is possible if the IR illumination from one device is shining into another device. I've seen experiments that involve mounting the Leap Motion device directly to the Oculus, so that could be another option.